AGATE

Agate is a microcrystalline variety of quartz (silica), chiefly chalcedony, characterised by its fineness of grain and brightness of color. Although agates may be found in various kinds of rock, they are classically associated with volcanic rocks but can be common in certain metamorphic rocks.

Colorful agates and other chalcedonies were obtained over 3,000 years ago from the Achates River, now called Dirillo, in Sicily.

The stone was given its name by Theophrastus, a Greek philosopher and naturalist, who discovered the stone along the shore line of the river Achates (Greek) sometime between the 4th and 3rd centuries BC. The agate has been recovered at a number of ancient sites, indicating its widespread use in the ancient world; for example, archaeological recovery at the Knossos site on Crete illustrates its role in Bronze Age Minoan culture. 

Formation and characteristics 

Most agates occur as nodules in volcanic rocks or ancient lavas where they represent cavities originally produced by the disengagement of volatiles in the molten mass which were then filled, wholly or partially, by siliceous matter deposited in regular layers upon the walls. Such agates, when cut transversely, exhibit a succession of parallel lines, often of extreme tenuity, giving a banded appearance to the section. Such stones are known as banded agate, riband agate and striped agate.

In the formation of an ordinary agate, it is probable that waters containing silica in solution -- derived, perhaps, from the decomposition of some of the silicates in the lava itself -- percolated through the rock and deposited a siliceous coating on the interior of the vapour-vesicles. Variations in the character of the solution or in the conditions of deposition may cause a corresponding variation in the successive layers, so that bands of chalcedony often alternate with layers of crystalline quartz. Several vapour-vesicles may unite while the rock is still viscous, and thus form a large cavity which may become the home of an agate of exceptional size; thus a Brazilian geode lined with amethyst and weighing 67 tons was exhibited at the Dusseldorf Exhibition of 1902. Perhaps the most comprehensive review of agate chemistry is a recent text by Moxon cited below.

The first deposit on the wall of a cavity, forming the "skin" of the agate, is generally a dark greenish mineral substance, like celadonite, delessite or "green earth", which are rich in iron probably derived from the decomposition of the augite in the enclosing volcanic rock. This green silicate may give rise by alteration to a brown iron oxide (limonite), producing a rusty appearance on the outside of the agate-nodule. The outer surface of an agate, freed from its matrix, is often pitted and rough, apparently in consequence of the removal of the original coating. The first layer spread over the wall of the cavity has been called the "priming", and upon this base zeolitic minerals may be deposited.

Many agates are hollow, since deposition has not proceeded far enough to fill the cavity, and in such cases the last deposit commonly consists of quartz, often amethyst, having the apices of the crystals directed towards the free space so as to form a crystal-lined cavity, or geode.

On the disintegration of the matrix in which the agates are embedded, they are set free. The agates are extremely resistant to weathering and remain as nodules in the soil or are deposited as gravel in streams and shorelines.

Uses in industry and art

Industry uses agates chiefly to make ornaments such as pins, brooches, paper knives, inkstands, marbles and seals. Because of its hardness and ability to resist acids, agate is used to make mortars and pestles to crush and mix chemicals. Because of the high polish possible with agate it has been used for centuries for leather burnishing tools. Idar Oberstein was one of the centers which made use of agate on an industrial scale. Where in the beginning locally found agates were used to make all types of objects for the European market, this became a globalized business around the turn of the 20th century: Idar-Oberstein imported large quantities of agate from Brazil, as ship's ballast. Making using of a variety of proprietary chemical processes, they produced colored beads that were sold around the globe. Agates have long been used in arts and crafts. The sanctuary of a Presbyterian church in Yachats, Oregon, has six windows with panes made of agates collected from the local beaches.